Solidification heat release of copper foam/low-melting-point alloy composite phase change material
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摘要:
为研究泡沫铜/低熔点合金(LMPA)复合相变材料在间歇放热工作环境下恢复至初始状态的能力及不同孔隙率泡沫铜的添加对其凝固放热过程的影响,通过数值模拟对比分析了47合金、正二十三烷与泡沫铜复合前后的凝固放热过程,并调节泡沫铜/47合金复合材料孔隙率计算模拟芯片温度在凝固放热过程中温度随时间变化曲线。结果表明:泡沫铜的添加对2类材料凝固过程均有促进作用,模拟芯片恢复至目标温度所需时间分别被缩短6.6%和47.7%。因体积潜热值的差距,泡沫铜/47合金凝固时需放出更多热量,恢复至目标温度的时间较长,是正二十三烷复合相变材料的1.52倍。随着孔隙率的增大,复合相变材料恢复至室温状态所用时长变化不大,考虑到孔隙率对相变热控过程中的影响,实际使用时应综合考虑。
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关键词:
- 低熔点合金(LMPA)复合材料 /
- 数值模拟 /
- 间歇性 /
- 凝固放热 /
- 孔隙率
Abstract:In order to research the competence of the copper foam/low-melting-point alloy (LMPA) composite material to recover to the initial state in the intermittent exothermic working environment and the influence of the addition of copper foam with different porosity on the solidification exothermic process, this paper compares and analyzes the solidification exothermic process of 47 alloys and n-tricosane before and after compositing with copper foam through numerical simulation, and adjusts the porosity of the copper foam/47 alloy composite material to calculate the temperature change curve of the simulation chip temperature during the solidification exothermic process. The results show that the addition of copper foam can promote the solidification process of the two types of materials, and the time of the simulation chip to recover to the target temperature is shortened by 6.6% and 47.7%. Due to the difference in volume latent heat value, the copper foam/47 alloy needs to release more heat during solidification, and it takes longer to recover to the target temperature, which is 1.52 times that of the n-tricosane composite. With the increase of porosity, the time that is taken for the composite phase change material to return to room temperature does not change much. Considering the influence of porosity on the thermal control process of phase change, comprehensive consideration should be given to actual use.
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表 1 材料物性参数
Table 1. Material's physical property parameters
物性参数 47合金 正二十三烷 泡沫铜 316L不锈钢 相变温度/℃ 51 47.6 潜热值/(kJ·kg-1) 32.4 234.4 密度/(kg·m-3) 9 160 797 8 978 8 030 比热容/(J·(kg·K)-1) 160 2 360 381 502.5 导热系数/(W·(m·K)-1) 11.7 0.21 387.6 16.27 黏度/(Pa·S) 1.1 0.014 8 热膨胀率/ T-1 2.44×10-5 9×10-4 -
[1] 陈秦. 石墨泡沫炭基相变储能材料传热分析[D]. 哈尔滨: 哈尔滨工程大学, 2013.CHEN Q. Heat transfer analysis of graph-ite goams infiltrated with phase change meterials for energy storage[D]. Harbin: Harbin Engineering University, 2013(in Chinese). [2] LANSANCE C J M, SIMONS R E. Advances in high-performance cooling for electronics[J]. Electronics Cooling, 2005, 11(4): 22-39. [3] ZILIO C, RIGHETTI G, MANCIN S, et al. Active and passive cooling technologies for thermal management of avionics in helicopters: Loop heat pipes and mini-vapor cycle system[J]. Thermal Science and Engineering Progress, 2018, 5: 107-116. doi: 10.1016/j.tsep.2017.11.002 [4] TONG X C. Advanced materials for thermal management of electronic packaging[M]. Berlin: Springer, 2011: 39-65. [5] STEINBERG D S. Cooling techniques for electronic equipment[M]. New York: Wiley, 1980. [6] MEHLING H, CABEZA L F, YAMAHA M. Phase change materials: Application fundamentals[M]//PAKSOY H O. Thermal energy storage for sustainable energy consumption. Berlin: Springer, 2007: 279-313. [7] 赵亮, 邢玉明, 刘鑫, 等. 基于硬脂酸复合相变材料的被动热沉性能[J]. 北京航空航天大学学报, 2019, 45(5): 970-979. doi: 10.13700/j.bh.1001-5965.2018.0513ZHAO L, XING Y M, LIU X, et al. Performance of a passive heat sink using stearic acid based composite as phase change material[J]. Journal of Beijing University of Aeronautics and Astronautics, 2019, 45(5): 970-979(in Chinese). doi: 10.13700/j.bh.1001-5965.2018.0513 [8] GE H, LI H, MEI S, et al. Low melting point liquid metal as a new class of phase change material: An emerging frontier in energy area[J]. Renewable & Sustainable Energy Reviews, 2013, 21(5): 331-346. [9] 葛浩山. 低熔点金属相变传热方法的研究与应用[D]. 北京; 中国科学院大学, 2013.GE H S. Research and application of phase transition heat transfer method for low melting point metals[D]. Beijing: University of Chinese Academy of Sciences, 2013(in Chinses). [10] 吴雨越. 基于低熔点合金的相变储能式散热器瞬态性能实验研究[D]. 杭州: 浙江大学, 2016.WU Y Y. Experimental study on transient performance of phase change energy storage radiator based on low melting point alloy[D]. Hangzhou: Zhejiang University, 2016(in Chinese). [11] WANG Z, ZHANG Z, JIA L, et al. Paraffin and paraffin/aluminum foam composite phase change material heat storage experimental study based on thermal management of Li-ion battery[J]. Applied Thermal Engineering, 2015, 78: 428-436. doi: 10.1016/j.applthermaleng.2015.01.009 [12] 丁小恒, 孟松鹤, 解维华, 等. 金属相变材料热沉传热试验与仿真[J]. 复合材料学报, 2013, 30(S1): 205-211. https://www.cnki.com.cn/Article/CJFDTOTAL-FUHE2013S1040.htmDING X H, MENG S H, XIE W H, et al. Experiment and simulation for metallic phase change materials heat sink[J]. Acta Materiae Compositae Sinica, 2013, 30(S1): 205-211(in Chinese). https://www.cnki.com.cn/Article/CJFDTOTAL-FUHE2013S1040.htm [13] 胡锦炎. 固液相变储能热沉的理论与实验研究[D]. 武汉: 华中科技大学, 2017.HU J Y. Theoretical and experimental research on thermal storage heat sink based on solid-liquid phase change[D]. Wuhan: Huazhong University of Science and Technology, 2017(in Chinese). [14] ZHAO L, XING Y, LIU X. Experimental investigation on the thermal management performance of heat sink using low melting point alloy as phase change material[J]. Renewable Energy, 2020, 146(2): 1578-1587. [15] MESALHY O, LAFDI K, ELGAFY A, et al. Numerical study for enhancing the thermal conductivity of phase change material (PCM) storage using high thermal conductivity porous matrix[J]. Energy Conversion and Management, 2005, 46(6): 847-867. doi: 10.1016/j.enconman.2004.06.010