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摘要:
为了提高激光波长调制光谱法(WMS)测量气体浓度的速度和准确度,首次提出了一种通过对吸收光谱谐波信号的主峰进行拟合的气体浓度测量方法。在该方法中,只扫描吸收光谱谐波信号的主峰部分来获得谐波信号(WMS-2
f /1f )的峰值点。因为缩减了吸收光谱的扫描范围,所以扫描速度得到了提高。通过对吸收光谱谐波信号(WMS-2f /1f )的主峰部分进行多项式拟合,进一步提高了测量精度。详细讨论了多项式阶数的确认方法,以及拟合数据长度对测量结果的影响。通过测量不同情况下的二氧化碳浓度验证了该方法的有效性。-
关键词:
- 波长调制光谱法(WMS) /
- 多项式拟合 /
- 吸收光谱 /
- 气体浓度 /
- 二氧化碳
Abstract:A fast and accurate gas concentration measurement method by fitting the main peak of the absorption spectrum harmonic signal is proposed for the first time to significantly improve the speed and accuracy of gas concentration measurement by laser wavelength modulation spectroscopy (WMS). In the proposed method, only the main peak of the absorption spectrum harmonic signal is scanned to obtain the peak value of the harmonic signal (WMS-2
f /1f ). This can greatly improve the scan speed due to the reduction of absorption spectrum scan range. Higher accuracy measurement can be achieved via fitting the main peak of the absorption spectrum harmonic signal (WMS-2f /1f ) by a polynomial. The methods for choosing a suitable polynomial's degree and the influence of fitting data length on measurement result are discussed in this paper. The experimental results of carbon dioxide concentration measurement under different conditions validate the effectiveness of the proposed method. -
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[1] PHILIPPE L C, HANSON R K.Laser diode wavelength-modulation spectroscopy for simultaneous measurement of temperature, pressure, and velocity in shock-heated oxygen flows[J].Applied Optics, 1993, 32(30):6090-6103. doi: 10.1364/AO.32.006090 [2] LIU C, XU L, LI F, et al.Resolution-doubled one-dimensional wavelength modulation spectroscopy tomography for flame flatness validation of a flat-flame burner[J].Applied Physics B, 2015, 120(3):407-416. doi: 10.1007/s00340-015-6150-9 [3] GOLDENSTEIN C S, SPEARRIN R M, SCHULTZ I A, et al.Wavelength-modulation spectroscopy near 1.4 μm for measurements of H2O and temperature in high-pressure and -temperature gases[J].Measurement Science and Technology, 2014, 25(5):055101. doi: 10.1088/0957-0233/25/5/055101 [4] CAI W, KAMINSKI C F.A tomographic technique for the simultaneous imaging of temperature, chemical species, and pressure in reactive flows using absorption spectroscopy with frequency-agile lasers[J].Applied Physics Letters, 2014, 104(3):034101. doi: 10.1063/1.4862754 [5] SPEARRIN R M, GOLDENSTEIN C S, JEFFRIES J B, et al.Quantum cascade laser absorption sensor for carbon monoxide in high-pressure gases using wavelength modulation spectroscopy[J].Applied Optics, 2014, 53(9):1938-1946. doi: 10.1364/AO.53.001938 [6] NEETHU S, VERMA R, KAMBLE S S, et al.Validation of wavelength modulation spectroscopy techniques for oxygen concentration measurement[J].Sensors and Actuators B:Chemical, 2014, 192:70-76. doi: 10.1016/j.snb.2013.10.070 [7] PENG Z M, DING Y J, CHE L, et al.Calibration-free wavelength modulated TDLAS under high absorbance conditions[J].Optics Express, 2011, 19(23):23104-23110. doi: 10.1364/OE.19.023104 [8] SUN K, CHAO X, SUR R, et al.Analysis of calibration-free wavelength-scanned wavelength modulation spectroscopy for practical gas sensing using tunable diode lasers[J].Measurement Science and Technology, 2013, 24(12):125203. doi: 10.1088/0957-0233/24/12/125203 [9] QU Z, GHORBANI R, VALIEV D, et al.Calibration-free scanned wavelength modulation spectroscopy-Application to H2O and temperature sensing in flames[J].Optics Express, 2015, 23(12):16492-16499. doi: 10.1364/OE.23.016492 [10] RIEKER G B, JEFFRIES J B, HANSON R K.Calibration-free wavelength-modulation spectroscopy for measurements of gas temperature and concentration in harsh environments[J].Applied Optics, 2009, 48(29):5546-5560. doi: 10.1364/AO.48.005546 [11] LIU J T C, JEFFRIES J B, HANSON R K.Wavelength modulation absorption spectroscopy with 2f detection using multiplexed diode lasers for rapid temperature measurements in gaseous flows[J].Applied Physics B, 2004, 78(3-4):503-511. doi: 10.1007/s00340-003-1380-7 [12] SCHULTZ I A, GOLDENSTEIN C S, JEFFRIES J B, et al.Diode laser absorption sensor for combustion progress in a model scramjet[J].Journal of Propulsion and Power, 2014, 30(3):550-557. doi: 10.2514/1.B34905 [13] GOLDENSTEIN C S, ALMODÓVAR C A, JEFFRIES J B, et al.High-bandwidth scanned-wavelength-modulation spectroscopy sensors for temperature and H2O in a rotating detonation engine[J].Measurement Science and Technology, 2014, 25(10):105104. doi: 10.1088/0957-0233/25/10/105104 [14] LIU J T C, RIEKER G B, JEFFRIES J B, et al.Near-infrared diode laser absorption diagnostic for temperature and water vapor in a scramjet combustor[J].Applied Optics, 2005, 44(31):6701-6711. doi: 10.1364/AO.44.006701 [15] BAYRAKLI I, AKMAN H.Ultrasensitive, real-time analysis of biomarkers in breath using tunable external cavity laser and off-axis cavity-enhanced absorption spectroscopy[J].Journal of Biomedical Optics, 2015, 20(3):037001. doi: 10.1117/1.JBO.20.3.037001 [16] SUN K, WANG S, SUR R, et al.Sensitive and rapid laser diagnostic for shock tube kinetics studies using cavity-enhanced absorption spectroscopy[J].Optics Express, 2014, 22(8):9291-9300. doi: 10.1364/OE.22.009291 [17] XU L, ZHANG J Q, YAN Y.A wavelet-based multisensor data fusion algorithm[J].IEEE Transactions on Instrumentation and Measurement, 2004, 53(6):1539-1545. doi: 10.1109/TIM.2004.834066