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辐射固化树脂体系合成原理研究

李敏 张佐光 仲伟虹 姚洪伟

李敏, 张佐光, 仲伟虹, 等 . 辐射固化树脂体系合成原理研究[J]. 北京航空航天大学学报, 2001, 27(3): 254-256.
引用本文: 李敏, 张佐光, 仲伟虹, 等 . 辐射固化树脂体系合成原理研究[J]. 北京航空航天大学学报, 2001, 27(3): 254-256.
LI Min, ZHANG Zuo-guang, ZHONG Wei-hong, et al. Synthesis of Electron Beam Curing Resins[J]. Journal of Beijing University of Aeronautics and Astronautics, 2001, 27(3): 254-256. (in Chinese)
Citation: LI Min, ZHANG Zuo-guang, ZHONG Wei-hong, et al. Synthesis of Electron Beam Curing Resins[J]. Journal of Beijing University of Aeronautics and Astronautics, 2001, 27(3): 254-256. (in Chinese)

辐射固化树脂体系合成原理研究

基金项目: 国家自然科学基金资助项目(59833110)
详细信息
  • 中图分类号: TB 332; O 644.2

Synthesis of Electron Beam Curing Resins

  • 摘要: 针对辐射固化复合材料树脂体系的原理,从引入具有辐敏性单体或基团入手,合成了活性稀释剂含硅丙烯酸酯和活性单体,如单官能、双官能的马来酰亚胺单体和芳香族酰亚胺单体,并对它们的结构进行了红外表征.实验结果表明,合成所得的树脂基体均可以实现辐射交联,且固化产物性能较优.

     

  • [1] Glauser T, Johansson M, Hult A. Electron-beam curing of thick thermoset composite matrices[J]. Polym, 1999,40:5297~6304. [2] Min Z, Qian X, Tsutomu T. Preparation and properties of novel poly(urethane-imide)s[J]. Polym, 1998,39:6883~6889. [3] Morel F, Devker C, Jonsson S,et al. Kinetic study of the photo-induced copolymerization of N-substituted maleimides with electron donor monomers[J].Polym, 1999,40:2447~2452. [4] Jefferson L H, David J T, Peter J P. Electron spin resonance study of the homopolymerization of aromatic bismaleimides[J]. Polym, 1998,39:5601~5067. [5] Takao L, Noriyuki Y, Masao T. Modification of two-component bismaleimids resin by blending (meth)allyl compounds as third components[J].Polym Int, 1999,(48):587~593. [6] Catherine A B, Daniel L G, Giuseppe R P, et al. Electron beam curable adhesive for out-of-autoclave bonding of large composite structures. In:Brown H L, Jones D H, eds. Proceeding of the 45th International SAMPE Symposium and Exhibition Science of Advanced Materials and Process Engineering Series. Long Beach:CA, 2000. 2187~2119. [7] James M S, Steven H M, Bruce K T. Interpenetrating polymer network (IPN) adhesives for electron beam cure. In:Brown H L, Jones D H, eds. Proceedings of the 45th International SAMPE Symposium and Exhibition Science of Advanced Materials and Process Engineering Series. Long Beach:CA, 2000.2211~2222. [8] Guasti F, Rosi E. Low energy electron beam curing for thick composite production[J]. Comp Part A, 1997, (28):965~972.
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出版历程
  • 收稿日期:  2000-04-30
  • 刊出日期:  2001-03-31

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