Citation: | ZHANG Yanfeng, YANG Zhengpeng, CHEN Jun, et al. In-situ optical probe measurement of ultra-low emission reduction flue gas[J]. Journal of Beijing University of Aeronautics and Astronautics, 2017, 43(2): 403-409. doi: 10.13700/j.bh.1001-5965.2016.0126(in Chinese) |
With the development of ultra-low emission reduction in coal-fired power plant, the requirement of monitoring technologies is becoming more and more rigid. A detector probe based on differential optics absorption spectroscopy (DOAS) and multi-wavelength extinction method is presented, which can be used to realize the in-situ measurement of SO2, particulate in flue gas, etc. The system was calibrated with the standard SO2 gas and polystyrene particulate, and both inversion concentrations agree well with real values. The error is less than 10%, the fitting line of seven SO2 measurement points has good linearity, and linear correlation coefficient is 0.999 64. The system was successfully applied to a coal-fired power plant in different operating conditions for a longer time continuous monitoring. Results show that the system has a good agreement between system monitoring and working conditions on SO2 and particulate in flue gas.
[1] |
PLATT U, PERNER D, PÄTZ H W.Simultaneous measurement of atmospheric CH2O, O3, and NO2 by differential optical absorption[J].Journal of Geophysical Research Atmospheres, 1979, 84(C10):6329-6335. doi: 10.1029/JC084iC10p06329
|
[2] |
PLATT U, PERNER D, HARRIS G W, et al.Observations of nitrous acid in an urban atmosphere by differential optical absorption[J].Nature, 1980, 285(5763):312-314. doi: 10.1038/285312a0
|
[3] |
刘文清, 崔志成, 刘建国, 等.大气痕量气体测量的光谱学和化学技术[J].量子电子学报, 2004, 21(2):202-210. http://www.cnki.com.cn/Article/CJFDTOTAL-LDXU200402010.htm
LIU W Q, CUI Z C, LIU J G, et al.Measurement of atmospheric trace gases by spectroscopic[J].Chinese Journal of Quantum Electronics, 2004, 21(2):202-210(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-LDXU200402010.htm
|
[4] |
谢品华, 刘文清, 郑朝晖, 等.差分光学吸收光谱(DOAS) 技术在烟气SO2监测中的应用[J].光子学报, 2000, 29(3):271-276. http://www.cnki.com.cn/Article/CJFDTotal-GZXB200003017.htm
XIE P H, LIU W Q, ZHENG Z H, et al.Differential optical absorption spectroscopy (DOAS) technique applied to monitor sulfur dioxide in flue gas[J].Acta Photonica Sinica, 2000, 29(3):271-276(in Chinese). http://www.cnki.com.cn/Article/CJFDTotal-GZXB200003017.htm
|
[5] |
李昂, 谢品华, 刘文清, 等.被动差分光学吸收光谱法监测污染源排放总量研究[J].光学学报, 2007, 27(9):1537-1542. http://www.cnki.com.cn/Article/CJFDTOTAL-GXXB200709001.htm
LI A, XIE P H, LIU W Q, et al.Monitoring of total emission volume from pollution sources based on passive differential optical absorption spectroscopy[J].Acta Optica Sinica, 2007, 27(9):1537-1542(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-GXXB200709001.htm
|
[6] |
郑朝晖, 刘文清, 宋炳超, 等.差分光学吸收光谱(DOAS) 技术在烟气监测中的应用研究[J].量子电子学报, 2001, 18(B12):65-69. http://www.cnki.com.cn/Article/CJFDTOTAL-LDXU2001S1014.htm
ZHENG Z H, LIU W Q, SONG B C, et al.Measurement of flue gas with differential optical absorption spectroscopy[J].Chinese Journal of Quantum Electronics, 2001, 18(B12):65-69(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-LDXU2001S1014.htm
|
[7] |
吴桢, 虞启琏, 张帆, 等.差分吸收光谱技术中吸收截面的测量[J].仪器仪表学报, 2004, 25(4):470-472. http://www.cnki.com.cn/Article/CJFDTOTAL-YQXB200404013.htm
WU Z, YU Q L, ZHANG F, et al.Measurement of absorption cross section in differential optical spectrometry[J].Chinese Journal of Scientific Instrument, 2004, 25(4):470-472(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-YQXB200404013.htm
|
[8] |
崔厚欣, 齐汝宾, 张文军, 等.差分吸收光谱法大气环境质量在线连续监测系统的设计[J].分析仪器, 2008(1):7-11. http://www.cnki.com.cn/Article/CJFDTOTAL-FXYQ200801006.htm
CUI H X, QI R B, ZHANG W J, et al.Design of an environmental air quality on-line continuous monitoring system based on differential optical absorption[J].Analytical Instrumentation, 2008(1):7-11(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-FXYQ200801006.htm
|
[9] |
蔡小舒, 李树荣, 付敬业, 等.差分吸收光谱法监测NO2浓度技术研究[J].工程热物理学报, 2003, 24(2):351-353. http://www.cnki.com.cn/Article/CJFDTotal-GCRB200302050.htm
CAI X S, LI S R, FU J Y, et al.Study on measuring concentration of NO2 with DOAS method[J].Journal of Engineering Thermophysics, 2003, 24(2):351-353(in Chinese). http://www.cnki.com.cn/Article/CJFDTotal-GCRB200302050.htm
|
[10] |
毛万朋, 蔡小舒, 程智海, 等.傅里叶变换滤波-差分吸收光谱法在烟气SO2在线监测中的应用研究[J].工程热物理学报, 2004, 25(增刊):205-208. http://www.cnki.com.cn/Article/CJFDTotal-GCRB2004S1054.htm
MAO W P, CAI X S, CHENG Z H, et al.Fourier transform filtering-The application of diferential optical absorption spectroscopy in the on-line SO2 monitoring system[J].Journal of Engineering Thermophysics, 2004, 25(Suppl.):205-208(in Chinese). http://www.cnki.com.cn/Article/CJFDTotal-GCRB2004S1054.htm
|
[11] |
邵理堂, 王式民, 汤光华, 等.颗粒物Mie散射对差分吸收光谱技术的影响[J].光学学报, 2009, 29(3):594-601. doi: 10.3788/AOS
SHAO L T, WANG S M, TANG G H, et al.Influence of particle Mie scattering on differential optical absorption spectroscopy[J].Acta Optica Sinica, 2009, 29(3):594-601(in Chinese). doi: 10.3788/AOS
|
[12] |
李素文, 谢品华, 李玉金, 等.基于小波变换的差分吸收光谱数据处理方法[J].光学学报, 2006, 26(11):1601-1604. http://www.cnki.com.cn/Article/CJFDTOTAL-GXXB200611000.htm
LI S W, XIE P H, LI Y J, et al.Wavelet transform based differential optical absorption spectroscopy data processing[J].Acta Optica Sinica, 2006, 26(11):1601-1604(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-GXXB200611000.htm
|
[13] |
李素文, 刘文清, 谢品华.基于卡尔曼滤波的差分光学吸收光谱法[J].华南理工大学学报(自然科学版), 2006, 34(10):113-116(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-HNLG200610024.htm
LI S W, LIU W Q, XIE P H, et al.Differential optical absorption spectroscopy based on Kalman filtering[J].Journal of South China University of Technology (Natural Science Edition), 2006, 34(10):113-116(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-HNLG200610024.htm
|
[14] |
徐峰, 蔡小舒, 苏明旭, 等.光谱消光法测量高压湿蒸汽的研究[J].动力工程学报, 2009, 29(3):254-260. http://www.cnki.com.cn/Article/CJFDTOTAL-DONG200903012.htm
XU F, CAI X S, SU M X, et al.Research on the measurement of high pressure wet steam by spectral light extinction method[J].Journal of Power Engineering, 2009, 29(3):254-260(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-DONG200903012.htm
|
[15] |
黎石竹, 蔡小舒, 高伟, 等.RGB三波段消光法测量细微颗粒粒度分布研究[J].光学学报, 2015, 35(7):188-195. http://www.cnki.com.cn/Article/CJFDTOTAL-GXXB201507027.htm
LI S Z, CAI X S, GAO W, et al.Measuring fine particle size with RGB three wavelength bands light extinction method[J].Acta Optica Sinica, 2015, 35(7):188-195(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-GXXB201507027.htm
|
[16] |
周斌, 刘文清, 齐锋, 等.差分吸收光谱法测量大气污染的测量误差分析[J].光学学报, 2002, 22(8):957-961. http://www.cnki.com.cn/Article/CJFDTOTAL-GXXB200208013.htm
ZHOU B, LIU W Q, QI F, et al.Error analysis in differential optical absorption spectroscopy[J].Acta Optica Sinica, 2002, 22(8):957-961(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-GXXB200208013.htm
|
[17] |
周斌, 刘文清, 刘峰, 等.差分吸收光谱仪测量上下限的确定[J].应用光学, 2001, 22(5):25-28. http://www.cnki.com.cn/Article/CJFDTOTAL-YYGX200105006.htm
ZHOU B, LIU W Q, LIU F, et al.The determination of upper and lower limits of differential optical absorption spectroscopy[J].Journal of Applied Optics, 2001, 22(5):25-28(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-YYGX200105006.htm
|