| Citation: | ZHANG Q S，LI D Q，LIAN X X. Study of corrosion and hydrogen evolution risk of waded lithium ion-battery[J]. Journal of Beijing University of Aeronautics and Astronautics，2024，50（7）：2083-2092 （in Chinese） doi: 10.13700/j.bh.1001-5965.2022.0617
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Lithium-ion battery wading events occur frequently, especially, often suffering high salinity wading events in coastal areas and maritime operations. In this paper, 18650 model batteries were used as samples to carry out experiments on the risk of corrosion and hydrogen evolution of waded lithium-ion batteries under different salinity conditions. The findings indicate that soaking lithium-ion batteries in an aqueous sodium chloride solution triggers the onset of electrolytic and electrochemical corrosion. The higher the salinity of the solution, the more significant this phenomenon is. The corrosion mainly occurs at the anode cap. With corrosion developing, the corrosion hole goes deep into the interior until the battery is completely damaged. There is a positive correlation between the mass loss rate and voltage drop of lithium battery in the wading process. Aluminum hydroxide, ferrous hydroxide, and ferric hydroxide make up the majority of the corrosion products. In the process, a large amount of hydrogen emerges from the cathode, and the hydrogen generation rate has a positive linear relationship with the concentration of salt solution. For relatively narrow space, it is very easy to reach the lower limit of a hydrogen explosion. After mild corrosion, the injection degree of the thermal runaway process of the battery is more severe, and the risk of combustion and explosion is relatively high. Furthermore, extreme corrosion will directly damage the battery's construction, rendering it totally useless.
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