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Volume 39 Issue 1
Jan.  2013
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Journal of Beijing University of Aeronautics and Astronautics  > 2013  >  (1): 100-104.
Zhang Mingchuan, Zhang Jin, Tang Diyiet al. Analysis of Axial-Flow Compressors Stall in Uniform and Distorted Inlet Flow[J]. Journal of Beijing University of Aeronautics and Astronautics, 1998, 24(6): 704-706. (in Chinese)
Citation: Liu Yanjun, Jin Tao, Xiang Min, et al. Preparation of borate-based metal compounds and their electrocatalytic activities[J]. Journal of Beijing University of Aeronautics and Astronautics, 2013, (1): 100-104. (in Chinese)
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Preparation of borate-based metal compounds and their electrocatalytic activities

  • School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191, China

  • Received Date: 14 Oct 2011
  • Publish Date: 31 Jan 2013
    Abstract
  • Borate-based metal compounds thin film such as cobalt-borate(CoBi), nickel-borate(NiBi), manganese-borate(MnBi), rhodium-borate(RhBi) and palladium-borate(PdBi) were prepared on the surface of indium tin oxide(ITO) through electrochemical method at room temperature in alkaline medium. These compounds were amorphous films by morphology and structure characterization. Comparing their catalytic activities in electrocatalytical water splitting for oxygen generation, CoBi, NiBi and RhBi show higher activity than MnBi and PdBi. Further research indicates that borate is beficial for the preparation of borate-based metal compounds, and as a proton acceptor, the concentration of HBO32- rised gradually as pH increases from 7 to 11, HBO32- can accept the proton produced from oxygen evolving process, improving the electrocatalytical water splitting. In addition, the as-synthesized catalysts could be self-repaired and recycled.

     

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    • References(16)
  • [1]
    Fujishima A,Honda K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238(5358):37-38
    [2]
    陈启元,兰可尹,周澜.半导体光解水研究进展[J].材料导报,2005,19(1):20-23
    Chen Qiyuan,Lan Keyin,Zhou Lan.Progress on semiconductor photocatalysts for water decomposition[J].Materials Review,2005,19(1):20-23(in Chinese)
    [3]
    Osterloh F E.Inorganic materials as catalysts for photochemical splitting of water[J].Chem Mater,2008,20(1):35-54
    [4]
    Kazuhiko M ,Kazunari D.Meeting the clean energy demand:nanostructure architectures for solar energy conversion[J].J Phys Chem C,2007,111(7):7851-7861
    [5]
    Bard A J,Fox M A.Artificial photosynthesis:solar splitting of water to hydrogen and oxygen[J].Acc Chem Res,1995,28(3):141-145
    [6]
    Sun Jianwei,Zhong D K,Gamelin D R.Composite photoanodes for photoelectrochemical solar water splitting[J].Energy Environ Sci,2010,3:1252-1261
    [7]
    Surendranath Y,Kanan M W,Nocera D G.Mechanistic studies of the oxygen evolution reaction by a cobalt-phosphate catalyst at neutral pH[J].J Am Chem Soc,2010,132(46):16501-16509
    [8]
    Kanan M W,Nocera D G.In situ formation of an oxygen-evolving catalyst in neutral water containing phosphate and Co2+[J].Science,2008,321(5892):1072-1075
    [9]
    Surendranath Y,Dincǎ M,Nocera D G.Electrolyte-dependent electrosynthesis and activity of cobalt-based water oxidation catalysts[J].J Am Chem Soc,2009,131(7):2615-2620
    [10]
    Lutterman D A,Surendranath Y,Nocera D G.A self-healing oxygen-evolving catalyst[J].J Am Chem Soc,2009,131(11):3838-3839
    [11]
    Kanan M W,Yano J,Surendranath Y,et.al.Structure and valency of a cobalt-phosphate water oxidation catalyst determined by in situ X-ray spectroscopy[J].J Am Chem Soc,2010,132(39):13692-13701
    [12]
    Mcalpin J G,Surendranath Y,Dinca M,et al.EPR evidence for Co(IV) species produced during water oxidation at neutral pH[J].J Am Chem Soc,2010,132(20):6882-6883
    [13]
    Zhong D K,Gamelin D R.Photoelectrochemical water oxidation by cobalt catalyst("Co-Pi")/α-Fe2O3 composite photoanodes:oxygen evolution and resolution of a kinetic bottleneck[J].J Am Chem Soc,2010,132(12):4202-4207
    [14]
    Zhong D K,Sun Jianwei,Inumaru H,et al.Solar water oxidation by composite catalyst/α-Fe2O3 photoanodes[J].J Am Chem Soc,2009,131(17):6086-6087
    [15]
    Steinmiller E M P,Choi K S.Photochemical deposition of cobalt-based oxygen evolving catalyst on a semiconductor photoanode for solar oxygen production[J].Proc Natl Acad Sci,2009,106(49):20633-20636
    [16]
    Dincǎ M,Surendranath Y,Nocera D G.Nickel-borate oxygen-evolving catalyst that functions under benign conditions[J].Proc Natl Acad Sci,2010,107(23):10337-10341
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