银纳米结构的电化学制备及表面增强拉曼效应

孙杰; 许頔; 刁鹏; 殷鹏刚

银纳米结构的电化学制备及表面增强拉曼效应

1.
北京航空航天大学材料科学与工程学院, 北京 100191
2. 北京航空航天大学化学与环境学院, 北京 100191

基金项目: 国家自然科学基金资助项目(20973020,21173016);高等学校博士学科点基金资助项目(20101102110002);新世纪优秀人才支持计划资助项目(NCET-08-0034)

详细信息

中图分类号: O614
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出版历程
- 收稿日期: 2011-11-26
- 网络出版日期: 2013-02-28

Electrochemical preparation of Ag nanostructures and their surface enhanced Raman scattering effects

1.
School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191, China
2. School of Chemistry and Environment, Beijing University of Aeronautics and Astronautics, Beijing 100191, China

摘要

摘要: 利用电化学沉积的方法在氧化铟锡(ITO,Indium Tin Oxide)导电玻璃表面成功地制备出了形貌均一的银纳米结构.所制备银纳米结构的形貌和密度与前驱体AgNO₃的浓度、沉晶种电位、生长电位以及柠檬酸钠的加入均有着重要的关系,只有合理地设置这些参数才能制得形貌和密度均较为理想的银纳米粒子.此外以对巯基苯胺(p-ATP,p-aminothiophenol)为探针分子,在633 nm的激光激发下对银纳米结构进行了表面增强拉曼效应(SERS,Surface Enhanced Raman Scattering)的研究,结果表明其在SERS领域有着潜在的应用价值.
- 银纳米结构 /
- 电化学 /
- 表面增强拉曼效应
Abstract: Ag nanostructures were successfully prepared on indium tin oxide(ITO) surfaces through electrochemical deposition. These nanostructures possessed uniform morphology. The concentration of AgNO₃, the nucleation potential, the growth potential and the addition of sodium citrate greatly affected the morphology and density of the as-prepared Ag nanostructures. Only when these parameters were reasonably set could Ag nanostructures with well-defined morphology and considerable density be obtained. Investigation on surface enhanced Raman scattering(SERS) activities of the as-prepared Ag nanostructures was also carried out under 633 nm excitation, using p-aminothiophenol (p-ATP) as the probe molecule. The results show that they can serve as potential SERS substrates.
- Ag nanostructures /
- electrochemistry /
- surface enhanced Raman scattering(SERS)

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参考文献(21)

[1]	吴跃辉,徐丽金.银杀菌材料及其杀菌作用[J].江西化工,2001(3):8-10 Wu Yuehui,Xu Lijin.Ag-carrying antibacterial materials and its property[J].Jiangxi Chemical Industry,2001(3): 8-10(in Chinese)
[2]	刘吉平,郝向阳.纳米科学与技术[M].北京:科学出版社,2002 Liu Jiping,Hao Xiangyang.Nanoscale science and technology[M].Beijing: Science Press,2002(in Chinese)
[3]	An J,Tang B,Ning X H,et al.Photoinduced shape evolution: from triangular to hexagonal silver nanoplates[J].Journal of Physical Chemistry C,2007,111(49):18055-18059
[4]	Wiley B.Polyol synthesis of silver nanostructures:control of product morphology with Fe(II) or Fe(III) species[J].Langmuir,2005,21(18):8077
[5]	Guo S,Dong S,Wang E.Rectangular silver nanorods:controlled preparation,liquid-liquid interface assembly,and application in surface-enhanced raman scattering[J].Crystal Growth & Design,2008,9(1):372-377
[6]	Liang H Y,Wang W Z,Huang Y Z,et al.Controlled synthesis of uniform silver nanospheres[J].Journal of Physical Chemistry C,2010,114(16):7427-7431
[7]	Zhang Q,Li W Y,Moran C,et al.Seed-mediated synthesis of Ag nanocubes with controllable edge lengths in the range of 30～200 nm and comparison of their optical properties[J].Journal of the American Chemical Society,2010,132(32):11372-11378
[8]	Dong X Y,Ji X H,Jing J,et al.Synthesis of triangular silver nanoprisms by stepwise reduction of sodium borohydride and trisodium citrate[J].Journal of Physical Chemistry C,2010,114(5):2070-2074
[9]	Liu G,Cai W,Liang C.Trapeziform Ag nanosheet arrays induced by electrochemical deposition on Au-coated substrate[J].Crystal Growth & Design,2008,8(8):2748-2752
[10]	Qin X,Wang H,Wang X,et al.Synthesis of dendritic silver nanostructures and their application in hydrogen peroxide electroreduction[J].Electrochimica Acta,2011,56(9):3170-3174
[11]	Tang S,Meng X,Lu H,et al.PVP-assisted sonoelectrochemical growth of silver nanostructures with various shapes[J].Materials Chemistry and Physics,2009,116(2/3):464-468
[12]	Zhang D,Diao P,Zhang Q.Potential-induced shape evolution of gold nanoparticles prepared on ITO substrate[J].Journal of Physical Chemistry C,2009,113(36):15796-15800
[13]	Diao P,Zhang D,Guo M,et al.Comments on electric-field-assisted growth of highly uniform and oriented gold nanotriangles on conducting glass substrates[J].Advanced Materials,2009,21(13):1317-1319
[14]	晏晓晖,刁鹏,项民. 形貌可控的钯纳米粒子的电化学制备及电催化性质[J].高等学校化学学报,2011,32(11): 2650-2656 Yan Xiaohui,Diao Peng,Xiang Min.Electrochemical preparation of shape-controlled Pd nanoparticles and their electrocatalytic properties[J].Chemical Journal of Chinese Universities,2011,32(11):2650-2656(in Chinese)
[15]	刘云彦,刁鹏,项民.电沉积法制备铂纳米粒子过程中卤素阴离子对粒子形貌及电催化性质的影响[J].化学学报,2011,69(11):1301-1307 Liu Yunyan,Diao Peng,Xiang Min.Effect of halide ions on the morphology and the electrocatalytic activity of platinum nanoparticles prepared by electrodeposition[J].Acta Chimica Sinica,2011,69(11):1301-1307(in Chinese)
[16]	Tang B,An J,Zheng X,et al.Silver nanodisks with tunable size by heat aging[J].Journal of Physical Chemistry C,2008, 112(47): 18361-18367
[17]	An J,Tang B,Ning X,et al.Photoinduced shape evolution:from triangular to hexagonal silver nanoplates[J].Journal of Physical Chemistry C,2007,111(49):18055-18059
[18]	Sun Y A,Xia Y N.Triangular nanoplates of silver:synthesis,characterization,and use as sacrificial templates for generating triangular nanorings of gold[J].Advanced Materials,2003, 15(9): 695-699
[19]	Wu X,Redmond P L,Liu H,et al.Photovoltage mechanism for room light conversion of citrate stabilized silver nanocrystal seeds to large nanoprisms[J].Journal of the American Chemical Society,2008,130(29):9500-9506
[20]	Osawa M,Matsuda N,Yoshii K,et al.Charge transfer resonance Raman process in surface-enhanced Raman scattering from p-aminothiophenol adsorbed on silver:Herzberg-Teller contribution[J].Journal of Physical Chemistry,1994,98(48):12702-12707
[21]	Huang Y F,Zhu H P,Liu G K,et al.When the signal is not from the original molecule to be detected:chemical transformation of para-aminothiophenol on Ag during the SERS measurement[J].Journal of the American Chemical Society,2010, 132(27): 9244-9246