Study of Microbiologically Influenced Corrosion of LY12 Aluminum Alloy with Atomic Force Microscopy
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摘要: 采用原子力显微镜对硫酸盐还原细菌引起的LY12铝合金腐蚀进行了研究.分别研究了不同质 量分数 的Fe2+, Cl-, SO2-4离子对硫酸盐还原细菌(SRB)引起的LY12铝合金腐 蚀 的影响.Fe2+质量分数的增加会使腐蚀程度增加.随着Cl-质量分数的增加,局部腐 蚀也会严 重.在一定质量分数范围内,SO2-4加速腐蚀;当超过一定质量分数后,SO2- 4会减 缓腐蚀.当SO2-4离子质量分数从0.80%增加到1.50%时,溶液腐蚀性有所降低.通过 原子力显微镜的研究,可以直观的说明电化学研究的结果和各影响因素的作用.Abstract: Sulfate-reducing bacteria induced corrosion of aluminum alloy LY12 was investig ated by using atomic force microscopy, as a function of concentrations of Fe 2+, Cl-, SO2-4 ions of the test solution. With in creasing Fe2+ concentration, the corrosion of LY12 alloy was obviously pro moted. Similar effect was observed with the addition of Cl- into the solution. The SO2-4 ion exhibited a promoting effect on corrosion at lo wer concentration and a reduced effect at higher concentration. According to th e result with AFM, the data measured by electrochemical method can be confirmed and showed, and the effect of Fe2+, Cl-, SO2-4 ions can be demonstrated by atomic force microscopy(AFM).
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Key words:
- sulfate-reducing bacteria /
- corrosion /
- aluminium alloys /
- atomic force microscop y
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[1] Hill E C.Microbial spoilage of light fuel oils .Pro Conf Microbial Corrosion . Feddington :NPL, 1983.108~109 [2] Videla H A.The action of cladosporiu resinae growth on the electrochemica l behavior of aluminum, biologically induced corrosion . International Confe rence on Biologically Induced Corrosion . Gaitherburg, 1985.215~222 [3] Wu Xiaoling, Liu Jianhua, Chen Xinyao. Surface analysis of aluminum alloy s influenced by sulfate-bacteria[J].Acta Metallurgica Sinica,1999,12(5):867 ~873 [4] 刘建华,李松梅.A3钢在厌氧环境中微生物腐蚀的实时电化学特性研究[J] 材料工程,2000,(增刊):96~98 Liu Jianhua, Li Songmei. Study of real-time electrochemical behavior of microbi ologically induced corrosion of A3 steel under anaerobic conditions [J]. Mater ial Engineering,2000,(supplement):96~98(in Chinese) [5] 刘建华,杨应广,李松梅. A3钢在厌氧环境中微生物腐蚀电化学特性研究 .材料保护,2000,33(11):32~33 Liu Jianhua, Yang Yingguang, Li Songmei. Study of electrochemical behavior of mi crobiologically induced corrosion of A3 steel under anaerobic conditions [J].M aterial Protection,2000,33(11):32~33(in Chinese) [6] Xu Lichong, Herbert H P, Chan K Y. Atomic force microscopy study of microbiologically influenced corrosion of mild steel[J].J Elecro chem Soc,1999,146(12):4455~4460 [7] 李松梅,孙 杰,刘建华. 海水体系中铝合金微生物腐蚀的研究[J].新材 料新技术,2001,12:31~32 Li Songmei, Sun Jie, Liu Jianhua. Study of microbiologically induced corrosion o f aluminum alloy in seawater [J].New Material New Technology,2001,12:31~32 (in Chinese) [8] 吴晓玲.厌氧环境中铝合金微生物腐蚀机理的研究 .北京:北京航空航 天大学材料科学与工程系,1999.43~95 Wu Xiaoling. Study of mechanism of microbiologically induced corrosion of alumin um alloy under anaerobic conditions . Beijing:Dept of Materials Science a nd Engineering, Beijing University of Aeronautics and Astronautics,1999.43~95 (in Chinese)
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