激光快速熔凝Al<sub>2</sub>O<sub>3</sub>/YAG共晶陶瓷的制备与组织

苏海军; 张军; 刘林; 傅恒志

激光快速熔凝Al₂O₃/YAG共晶陶瓷的制备与组织

西北工业大学凝固技术国家重点实验室, 西安 710072

基金项目: 国家自然科学基金资助项目(50102004); 航空基础科学基金资助项目(04G53048); 高等学校博士点专项科研基金资助项目(20040699035); 西北工业大学基础研究基金资助项目(NPU-FFR-W018101); 西北工业大学英才培养计划资助项目

详细信息

作者简介:
苏海军(1981-),男,陕西咸阳人,博士生,shjnpu@yahoo.com.cn.

中图分类号: TB 332;TF 125.4⁺.2
计量
- 文章访问数: 3097
- HTML全文浏览量: 56
- PDF下载量: 2103
- 被引次数: 0
出版历程
- 收稿日期: 2006-06-28
- 网络出版日期: 2007-07-31

Processing and microstructure of Al₂O₃/YAG eutectic ceramic by laser rapid remelting

State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi′an 710072, China

摘要

摘要: 采用激光快速熔凝技术制备Al₂O₃/YAG共晶自生复合陶瓷, 研究Al₂O₃/YAG共晶陶瓷在高能激光束作用下,不同扫描速率(0.01~2.0mm/s)、超高温度梯度下的凝固组织特征及其生长机制,探索激光熔凝过程控制参数与凝固组织的关系.研究结果表明:激光熔凝Al₂O₃/YAG共晶陶瓷由无规则连续分布的Al₂O₃相和YAG相两相组成,没有晶界和其他相,Al₂O₃相的体积分数为(45.0±2.0)%,两相耦合生长,交错分布,是典型的快速凝固层片状非规则共晶组织;共晶层间距细密, 并随激光扫描速度的增大而减小,扫描速度为0.02mm/s 时,共晶间距约为1~2μm,扫描速度为2.0mm/s时,共晶间距仅为0.5μm左右;综合热分析表明,Al₂O₃/YAG共晶熔点为2096K,与相图吻合.
- 激光熔凝 /
- Al₂O₃/YAG /
- 共晶自生复合陶瓷 /
- 微观组织 /
- 高温度梯度
Abstract: Laser rapid remelting experiments were conducted on the preparation of Al₂O₃/YAG eutectic ceramic in-situ composite to investigate the microstructure characteristic and growth behavior under an ultra-high temperature gradient and different laser scanning rates of 0.01~2.0mm/s, and to explore the relationship between the laser processing parameters and the microstructure. The results show that the laser remelted Al₂O₃/YAG eutectic is composed of irregularly and continuously distributed Al₂O₃ and YAG phases without grain boundary and any other phase. The volume fraction of Al₂O₃ is (45.0±2.0)%. The two phases couple each other and complexly interweave, in which the microstructure belongs to the typical lamellar structure of rapidly solidified anomalous eutectic. The eutectic spacing is very small and decreases from about 1~2μm to 0.5μm as the laser scanning rate increases from 0.02~2.0mm/s. The synthetical themal analysis(STA) shows that the eutectic temperature of Al₂O₃/YAG is 2096K, matching the phase diagram of Al₂O₃-Y₂O₃ system.
- laser remelting /
- Al₂O₃/YAG /
- eutectic ceramic in-situ composite /
- microstructure /
- high temperature gradient

HTML全文

参考文献(1)

[1] Waku Y, Nakagawa N, Wakamoto T, et al. A ductile ceramic eutectic composite with high strength at 1873K [J]. Nature, 1997, 389:49-52 [2] Sayir A. Directional solidification of eutectic ceramics [M]. Oxford:Oxford University Press, 1999:1-7 [3] Pastor J Y, Llorca J, Salazar A, et al. Mechanical properties of melt-grown alumina-yttrium aluminum garnet eutectics up to 1900K [J]. J Am Ceram Soc, 2005, 88(6):1488-1495 [4] 王华明,张凌云,李安,等. 金属材料快速凝固激光加工成形[J]. 北京航空航天大学学报,2004,30(10):962-967 Wang Huaming, Zhang Lingyun, Li An, et al. Rapid solidification laser processing and forming of advaced aeronautical metallic materials[J]. Journal of Beijing University of Aeronautics and Astronautics, 2004,30(10):962-967(in Chinese) [5] 张军, 苏海军, 刘林. Al₂O₃/YAG共晶自生复合陶瓷的激光熔凝实验研究[J]. 航空材料研究学报,2003,23:171-174 Zhang Jun, Su Haijun, Liu Lin. Experiment research on Al₂O₃/YAG eutectic ceramic in-situ composite with laser remelting [J]. J Aeronautical Mater, 2003, 23:171-174(in Chinese) [6] Jackson K A, Hunt J D. Lamellar and rod eutectic growth [J]. Trans AIEE, 1966, 236:1129-1142 [7] Matson L E, Hecht N. Microstructural stability and mechanical properties of directionally solidified alumina/YAG [J]. J Eur Ceram Soc, 1999, 19:2487-2501 [8] 杨森,黄卫东,林鑫,等. 激光快速凝固条件下Al-5.6wt%Mn合金的组织选择规律研究[J]. 应用激光,1999,19(5):243-246 Yang Sen, Huang Weidong, Lin Xin, et al. Study on microstructure selection of Al-5.6wt%Mn alloy under laser rapid solidification condition [J]. Applied Laser, 1999, 19(5):243-246(in Chinese) [9] Francisco I D, Merino R I, Orera V M, et al. Growth of Al₂O₃/ZrO₂ (Y₂O₃) eutectic rods by the laser floating zone technique:effect of the rotation [J]. J Eur Ceram Soc, 2005, 25(8):1341-1350 [10] Yasuda H, Ohnaka I, Sugiyama A, et al. Undercooled melt shaping of Al₂O₃-YAG eutectic composite by melting the Al₂O₃-YAP eutectic structure [J]. Mater Sci Forum, 2005(475-479):2709-2712 [11] Caslavsky J L, Viechnicki D J. Melting behavior of metastability of yttrium aluminum garnet (YAG) and YAlO₃determined by optical difference thermal analysis [J]. J Mater Sci, 1980, 15(7):1709-1718 [12] Mizutani Y, Yasuda H, Ohnaka I, et al. Phase selection of the Al₂O₃-Y₂O₃ system controlled by nucleation [J]. Mater Trans, 2000, 42(2):238-244

施引文献

资源附件(0)

访问统计