溶胶-水热法合成PZT纳米粉体及性能研究

林海波; 刘海涛; 王富耻; 曹茂盛

溶胶-水热法合成PZT纳米粉体及性能研究

北京理工大学材料科学与工程学院, 北京 100081

详细信息

作者简介:
林海波(1981-),男,浙江台州人,博士生,linhaiboom@126.com

中图分类号: TQ 174
计量
- 文章访问数: 3300
- HTML全文浏览量: 50
- PDF下载量: 1246
- 被引次数: 0
出版历程
- 收稿日期: 2006-06-18
- 网络出版日期: 2007-07-31

PZT nanoparticles synthesized by sol-hydrothermal method and properties

School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China

摘要

摘要: 结合溶胶-凝胶和水热法的优点,采用改进的溶胶-水热复合法在较低温下制备出纯相PZT纳米粉体,并对粉体的烧结性能进行了研究,分别讨论了烧结温度、保温时间等工艺参数对烧结陶瓷密度、微观结构和压电性能的影响.270℃保温热处理2h可合成出粒径约为20~30nm,具有良好分散性的钙钛矿型PZT纳米粉体,且具有良好的烧结活性.在1150℃烧结保温2h,压电性能达到最优(机电耦合系数: 0.50,机械品质因数: 410,压电常数: 220pC/N,介电常数: 1060).结果表明,溶胶水热复合法具有合成温度低、组分易于控制、粉体烧结活性高的优点.
- 溶胶 /
- 水热 /
- 锆钛酸铅(PZT) /
- 纳米粉体 /
- 压电陶瓷
Abstract: PZT nanopowders were fabricated at low temperature by modified sol-hydrothermal method, and the effects of the sintering parameter such as sintering temperature, keeping time on the density, grain size, piezoelectric and dielectric properties of the PZT ceramic were investigated. The results show that the particle size distribution of the PZT nanopowders synthesized 270℃ is homogeneous with pure perovskite structure (20~30nm). The optimal properties of the obtained piezoelectric PZT ceramic sintered at 1150℃ for 2h are planna electromechanical coupling factor: 0.50, mechanical quality factor: 410, piezoelectric constant: 220pC/N, dielectric constant: 1060, respectively. Compared with conventional solid reaction methods for PZT powders, the advantage of the modified sol-hydrothermal method are low synthesis temperature and high sintering activity of the powders.
- sol /
- hydrothermal /
- PZT /
- nanoparticles /
- piezoelectric ceramics

HTML全文

参考文献(1)

[1] Haertling Gene H. Ferroelectric ceramics:history and technology [J]. Journal of the American Ceramic Society, 1999, 82 (4):797-818 [2] He Zeming, Ma J, Zhang Ruifang, et al., PZT-based materials with bilayered structure:preparation and ferroelectric properties [J]. Journal of the European Ceramic Society, 2003, 23:1943-1947 [3] Saito H, Takkao T, Tani T, et al. Lead-free piezoceramics [J]. Nature, 2004, 432:84-87 [4] Eric Cross. Lead-free at last [J]. Nature, 2004, 432(4):24-25 [5] Garnweitner G, Hentschel J, Antonietti M, et al. Synthesis of amorphous powder precursors for nanocrystalline PbTiO₃, Pb(Zr,Ti)O₃, and PbZrO₃ [J]. Chemstry of Materials, 2005, 17(18):4594-4599 [6] Corker D L, Whatmore R W, Ringgaard E. Liquid- phase sintering of PZT ceramics [J]. Journal of the European Ceramic Society, 2000, 20:2039-2045 [7] 赵国伟, 黄海, 夏人伟. 柔性自适应桁架及其振动最优控制实验[J]. 北京航空航天大学学报, 2005, 31(4):434-438 Zhao Guowei, Huang Hai, Xia Renwei. Flexible adaptive truss testbed and its optimal control experiment for vibration [J]. Journal of Beijing University of Aeronautics and Astronautics, 2005, 31(4):434-438(in Chinese) [8] Surowiak Z, Kupriyanoy M F, Czekaj D. Properties of nanocrystalline ferroelectric PZT ceramics [J]. Journal of the European Ceramic Society, 2001, 21:1377-1381 [9] Linardos S, Zhang Q, Alcock J R. Preparation of sub-micron PZT particles with the sol-gel technique [J]. Journal of the European Ceramic Society, 2006, 26(1-2):117-123 [10] Suchanek W L, Lencka M, McCandlish L. Hydrothermal deposition of <001> oriented epitaxial Pb(Zr,Ti)O₃ films under varying hydrodynamic conditions [J]. Crystal Growth Design, 2005, 5(5):1715-1727 [11] Gong Wen, Li Jingfeng, Chu Xiangcheng, et al. Effect of pyrolysis temperature on preferential orientation and electrical properties of sol-gel derived lead zirconate titanate films [J]. Journal of the European Ceramic Society, 2004, 24(10/11):2977-2982

施引文献

资源附件(0)

访问统计