高级浅色歧化松香的制备工艺及脱色机理分析

朱岳麟; 汤丽妮; 郭红

高级浅色歧化松香的制备工艺及脱色机理分析

北京航空航天大学材料科学与工程学院, 北京 100083

详细信息

作者简介:
朱岳麟(1956-),男,湖南岳阳人,教授,ylzhu@buaa.edu.cn.

中图分类号: TQ 315.47
计量
- 文章访问数: 5121
- HTML全文浏览量: 274
- PDF下载量: 1559
- 被引次数: 0
出版历程
- 收稿日期: 2005-06-08
- 网络出版日期: 2006-03-31

Preparing technics and decoloring mechanism analysis of high-grade dispropriated rosin decoloration

School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100083, China

摘要

摘要: 针对目前国内市场上歧化松香产品颜色过深的问题,采用SQH-9新型脱色剂,对广西梧州松脂股份有限公司生产的歧化松香进行还原脱色精制研究,确定出温度、时间以及脱色剂投加量等最佳工艺条件,并采用红外、紫外光谱分析手段对其脱色前后样品进行了分析.结果表明,SQH-9脱色法可将一级歧化松香和特级歧化松香的加纳色号分别从7和5降至2,且脱色后歧化松香的乙醇溶液的紫外吸收曲线与日本进口歧化松香的乙醇溶液基本重合.由于SQH-9脱色剂价廉易得,因此具有很好的生产应用前景.
- 歧化松香 /
- 脱色精制 /
- 脱色机理
Abstract: Aimed at the over tint problem of disproportionated rosin in present demostic market, SQH-9 was used as a new decloring reagent,in order to deoxidize and refine disproportionated rosin, which was produced by Guangxi Wuzhou Rosin Ltd. The best decloring technic conditions were decided, including temprature,time and the dosage of decloring reagent, and the decoring mechanism was analyzed with UV as well as IR analyzing methods. Experimental results show that under the best decloring technics, SQH-9 decloring reagent can reduce the Garner color of first-class disproportionated rosin from 7 Garner color number to 2,while reducing the superfine disproportionated rosin from 5 Garner color number to 2,and the UV absorbing curves of ethanol solutions of disproportionated rosin declored by SQH-9 are basically superposing with that of the disproportionated rosin imported from Japan.Also SQH-9 is cheap and available in demostic market, it has good applying prospect in rosin industry.
- disproportionated rosin /
- decoloration refining /
- decoloration mechanism

HTML全文

参考文献(1)

[1] 傅光华,松香及松香施胶剂的现状与前景分析[J]. 造纸信息,2004,(2):9~12 Fu Guanghua.The actuality and foreground analysis of rosin and agglutinant[J].China Paper Newsletter, 2004,(2):9~12(in Chinese) [2] Smith P A, Son P S, Callaghan P M, %et al%. Sampling and analysis of airborne resin acids and solvent-soluble material derived from heated colophony (rosin) flux a method to quantify exposure to sensitizing compounds liberated during electronics soldering .http://gb.cnmade.com.cn/wenxian/cavm60bvvh.htm.1996-07-17 [3] Wassner D F, Ravetta D A. Temperature effects on leaf properties, resin content,and composition in Grindelia chiloensis (asteraceae)[J].Industrial Crops and Products, 2005,21(2):155~163 [4] 黄宝祥,罗宜新.国内松香施胶剂的现状和发展趋势[J].江西林业科技,1999,6,45~48 Huang Baoxiang,Luo Yixin. The actuality and development of rosin agglutinant .Jiangxi Forestry Science and Technology, 1999,6:45~48(in Chinese) [5] 栗子安,杨必胜,郭长泰.松香发红变质实验[J].林产化学与工业,1997,17(4):48~54 Li Zi'an, Yang Bisheng, Guo Changtai. Rubefaction and metamorphose experiment ofrosin[J]. Chemistry and Industry of Forestry Products, 1997,17(4):48~54(in Chinese) [6] 赵藻藩,周性尧,张悟铭,等.仪器分析[M].北京:高等教育出版社, 2000.56~59,67~69,99~103 Zhao Zaofan, Zhou Xingnao, Zhang Wuming, %et al%. Instrument analysis[M].Beijing:Higher Education Press, 2000.56~59,67~69,99~103(in Chinese) [7] 吴宗华,陈少平.不同气体介质中脂松香的热氧化行为[J].福建师范大学学报(自然科学版),2000,16(1):64~66 Wu Zonghua, Chen Shaoping. Oxidation behaviors of gum rosin heated in atmospheres of various gases[J]. Transaction of Fujian Teachers University(Natural Edition),2000,16(1):64~66(in Chinese) [8] 贺近恪,李启基.林产化学工业全书[M].北京:中国林业出版社, 2001.1071~1393 He Jinke, Li Qiji. Chemistry and industry of forestry cyclopaedia[M]. Beijing:Beijing Forestry Press, 2001.1071~1393(in Chinese)

施引文献

资源附件(0)

访问统计