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摘要:
复合材料热压罐成型过程中的固化度差值是复合材料固化度均匀性的主要表征参数之一。基于3层BP神经网络,以复合材料双平台固化工艺曲线的加热速率、保温时间和保温温度为输入参数,建立了成型过程任一时刻最大固化度差值的快速估算模型。仿真复合材料热压罐成型过程,得到最大固化度差值作为试验样本数据,对BP神经网络进行训练,训练结束后对该模型的准确性进行验证。结果表明:该BP神经网络估算模型准确性和效率较高,为复合材料热压罐成型最大固化度差值的估算提供了一种快速有效的新方法。
Abstract:The difference in degree of cure in the forming process of composite autoclave is one of the main characterization parameters of degree of cure uniformity of composite. Based on thethree-layer BP neural network, this paper established a rapid estimation model of maximum difference of curing degree at any time in the forming process with heating rate, holding time and holding temperature as input parameters. Maximum difference in degree of cure was obtained by simulating the forming process of composite autoclave as test sample data to train the BP neural network, and the accuracy of the model was verified after the training. The results show that the accuracy and efficiency of this BP neural network model are high, which provides a fast and effective new method for estimating the difference of the maximum curing degree of composite autoclave.
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Key words:
- composite /
- neural network /
- estimation /
- curing process /
- autoclave /
- residual stress
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表 1 复合材料AS4/3501-6热力学及固化动力学模型参数
Table 1. Thermodynamics and cure kinetics model parameters for AS4/3501-6 composites
参数 数值 ρ/(kg·m-3) 1 578 Cp/(J·(kg·K)-1) 862 kT/(W·(m·K)-1) 0.413 5 kL/(W·(m·K)-1) 12.83 Hr/(J·kg-1) 198.6×103 A1/min-1 2.102×109 A2/min-1 -2.014×109 A3/min-1 1.960×105 ΔE1/(J·mol-1) 8.07×104 ΔE2/(J·mol-1) 7.78×104 ΔE3/(J·mol-1) 5.66×104 注:ρ为复合材料的密度; Cp为比热; kT和kL分别为复合材料的横向和纵向导热系数; Hr为最终反应热; Ai(i=1, 2, 3)为频率因子; ΔEi(i=1, 2, 3)为活化能。 表 2 工艺参数取值范围
Table 2. Range of process parameters
参数 取值范围 a1/(℃·min-1) [1,5] a2/(℃·min-1) [1,5] T1/℃ [115,155] T2/℃ [175,215] tp/min [0, 100] tg/min [0, 150] 表 3 固化数据
Table 3. Curing data
a1/(℃·min-1) a2/(℃·min-1) T1/℃ T2/℃ tp/min tg/min Δα 3 3 120 180 120 60 0.008 23 3 3 121 180 120 60 0.008 23 3 3 119 180 120 60 0.008 36 4 3 120 179 120 60 0.008 04 2 3 120 179 120 60 0.007 96 2 4 120 179 120 60 0.008 50 2 2 120 179 120 60 0.006 78 2 2 120 179 123 60 0.006 78 1 1 116 176 102 72 0.003 48 1 1 116 175 93 78 0.003 42 1 1 116 176 93 78 0.003 42 1 2 116 175 93 78 0.005 89 1 1 116 175 90 78 0.003 42 1 1 116 175 96 78 0.003 41 1 1 116 175 96 80 0.003 39 1 1 115 177 66 100 0.003 26 1 1 121 175 78 100 0.002 92 1 1 121 177 78 100 0.002 92 1 1 130 175 78 100 0.002 33 1 1 130 176 78 100 0.002 34 表 4 Δα的估算
Table 4. Estimation of Δα
a1/(℃·min-1) a2/(℃·min-1) T1/℃ T2/℃ tp/min tg/min Δα的试验值Δαs Δα的估算值Δαg 误差值Δ=Δαs-Δαg 误差率Δ/Δs 3 3 120 181 120 60 0.008 56 0.008 09 0.000 47 0.054 2 2 120 179 123 60 0.006 78 0.006 53 0.000 25 0.036 1 1 119 178 120 60 0.003 82 0.003 89 -0.000 07 -0.018 1 1 117 117 114 64 0.003 69 0.003 66 0.000 03 0.008 1 1 115 175 90 88 0.003 38 0.003 50 -0.000 12 -0.035 -
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