Development of theories on polymer-based nanocomposites
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摘要: 讨论了国内外关于聚合物基纳米复合材料的理论研究,包括聚合物/层状结构硅酸盐PLS(Polymer-Layer Silicate)纳米复合材料的热力学、动力学和微观力学,以及聚合物/颗粒状无机纳米复合材料的纳米微粒分散原理、纳米粒子尺寸与复合材料性能之间的关系等.Abstract: A review of the development of theories on polymer-based nanocomposites was presented. Attention was focused on the researches of thermodynamics, kinetics and micro-mechanics of polymer/layered silicate nanocomposites. The theoretical investigation on polymer/inorganic particle nanocomposites were also involved. The dispersion mechanism of nano particles and the relationship between the dimensions of nano particles and properties of composites were discussed. The quantitative characterization of the influence of nano-sized filler on the polymer matrix is the most needed.
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Key words:
- polymer /
- nanocomposite /
- layered silicate /
- nano-particle
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[1] Beckera O, Varleyb R, Simon G. Morphology, thermal relaxations and mechanical properties of layered silicate nanocomposites based upon high-functionality epoxy resins[J]. Polymer,2002,43:4365~4373 [2]Chan C M, Wu J S, Li J X, et al. Polypropylene/calcium carbonate nanocomposites[J].Polymer,2002,43:2981~2992 [3]Lee T W,Park O O,Hong J M,et al.Carrier mobilities of polymer/organo-clay nanocomposite electroluminescent devices[J].Thin Solid Films,2001,393:347~351 [4] 黄 丽,孙正滨,张金生.复合材料领域中的纳米技术进展[J].复合材料学报,2001,18(3):1~4 Huang Li, Sun Zhengbin, Zhang Jinsheng. Progress of nano-technology in composites[J]. Acta Materiae Compositae Sinica, 2001,18(3):1~4(in Chinese) [5] 华幼卿,章正熙,黄玉强.聚烯烃纳米复合材料研究进展Ⅰ聚烯烃/粘土纳米复合材料[J].高分子材料科学与工程,2002,18(2):1~5 Hua Youqing, Zhang Zhengxi, Huang Yuqiang. Development on the study of polyolefin nanocomposites[J]. Polymeric Materials Science and Engineering, 2002,18(2):1~5(in Chinese) [6] 李 钟,李 强.聚合物/层状硅酸盐纳米复合材料制备原理[J].中国塑料,2001,15(6):29~34 Li zhong,Li qing.Preparation principles of polymer/layered silicate nanocomposites[J].China Plastics,2001,15(6):29~34(in Chinese) [7] 陈光明,李 强,漆宗能,等.聚合物/层状硅酸盐纳米复合材料研究进展[J].高分子通报, 1999,4:1~10 Chen Guangming,Li qiang,Qi Zongneng,et al. Advance in polymer layered silicate nanocomposites[J].Polymer Bulletin,1999,4:1~10(in Chinese) [8] Oya A, Kurokawa Y, Yasuda H. Factors controlling mechanical properties of clay mineral/polypropylene nanocomposites[J]. Journal of Materials Science, 2000,35:1045~1050 [9]Kornmanna X, Lindbergb H, Berglunda L A. Synthesis of epoxy-clay nanocomposites:influence of the nature of the clay on structure[J]. Polymer,2001,42:1303~1310 [10]Balazs A C, Singh C, Ginzburg V V. Calculating phase diagrams of polymer-clay mixtures by combining density functional and self-consistent field theory[J]. Materials Research Society Symposium Proceedings,1999:143~148 [11]Ginzburg V V, Singh C, Balazs A C. Theoretical phase diagrams of polymer/clay composites:the role of grafted organic modifiers[J].Macromolecules,2000,33:1089~1099 [12] 吕建坤,柯毓才,漆宗能,等.环氧/粘土纳米复合材料的形成机理与性能. 高分子通报,2000,6:18~13 Lv Jiankun, Ke Yucai, Qi Zongneng, et al. Formation mechanism and properties of epoxy/clay nanocomposites[J]. Polymer Bulletin, 2000,6:18~26(in Chinese) [13] Vaia R A, Giannelis E P. Lattice model of polymer melt intercalation in organically-modified layered silicates[J]. Macromolecules,1997,30:7990~7999 [14]Balazs A C, Singh C, Zhulina E. Modeling the interactions between polymers and clay surfaces through self-consistent field theory[J]. Macromolecules,1998,31(23):8370~8381 [15] 王立新,蹇锡高,袁金凤,等.环氧树脂-蒙脱石纳米复合材料制备与形成机理[J].大连理工大学学报,2000,40:6681~6684 Wang Lixin,Jian Xigao,Yuan Jinfeng, et al. Preparation of epoxy-montmorillonite nanocomposite and its formation mechanism[J].Journal of Dalian University of Technology,2000,40:6681~6684(in Chinese) [16] Vaia R A, Jandt K D, Kramer E J, et al. Kinetics of polymer melt intercalation[J]. Macromolecules,1995,28:8080~8085 [17]Krishnamoorti R, Vaia R A, Giannelis E P. Structure and dynamics of polymer-layered silicate Nanocomposites[J]. Chemistry of Materials, 1996,8(8):1728~1734 [18]Douglas A B, Jozef B. Micromechanics of nanocomposites:comparison of tensile and compressive elastic moduli, and prediction of effects of imcomplete exfoliation and imperfect anlignment on moudulus[J]. Polymer,2002,43:369~387 [19] 王立新,张福强,姜云鹏,等. PPy/SiO2纳米复合材料导电机理的研究[J].功能材料,1999,30(3):302~303 Wang Lixin, Zhang Fuqiang, Jiang Yunpeng, et al. Investigation on the conducting mechanism of PPy/SiO2 nanocomposite[J]. Journal of Functional Materials, 1999,30(3):302~303(in Chinese) [20] 鄢 程,李竟先,潘志东. 纳米TiO2颗粒的表面改性研究进展[J]. 陶瓷学报,2002,23(1):62~66 Yan Cheng, Li Jingxian, Pan Zhidong. Progress in the surface moldification research of nano-TiO2 particles[J]. Journal of Ceramics, 2002,23(1):62~66(in Chinese) [21] 罗忠富,黄 锐,卢 艾,等. 纳米CaCO3增强增韧HDPE复合材料的研究[J]. 中国塑料,2000,14(8):25~29 Luo Zhongfu, Huang Rui, Lu Ai, et al. Study on HDPE composite rein forced and toughened by nano CaCO3[J]. China Plastics, 2000,14(8):25~29(in Chinese) [22] 左美祥,黄志杰,张玉敏,等. 纳米SiOX在涂料中的分散作用[J]. 化工新型材料,2000,28(11):22~24 Zuo Meixiang, Huang Zhijie, Zhang Yumin, et al. The scatter function of nanometer SiOx in the paint[J]. New Chemical Materials, 2000,28(11):22~24(in Chinese) [23] 于化顺,闵光辉,陈熙琛. 固体粒子进入熔体的条件及影响因素[J]. 复合材料学报,2000,17(3):113~115 Yu Huashun, Min Guanghui, Chen Xichen. Conditions of the entry of solid particles into melt and influence factors on it[J]. Acta Materiae Compositae Sinica, 2000,17(3):113~115(in Chinese) [24] 吴春蕾,章明秋,容敏智. 低填充SiO2/聚丙烯纳米复合材料的拉伸特性. 材料工程,2001,5:30~33 Wu Chunlei, Zhang Mingqiu, Rong Minzhi. Tensile characteristics of low filler loaded SiO2/PP nanocomposites[J]. Journal of Materials Engineering, 2001,5:30~33(in Chinese) [25] 王 旭,黄 锐,金春洪,等. PP/弹性体/纳米CaCO3复合材料的研究[J]. 中国塑料,2000,14(6):34~38 Wang Xu, Huang Rui, Jin Chunhong, et al. Study on PP/elastomer/nano-CaCO3 composite[J]. China Plastics, 2000,14(6):34~38(in Chinese) [26] 李 远,陈建国,陈腊琼,等. PP /纳米CaCO3分散体系的研究[J]. 塑料工业,2001,29(1):16~17,20 Li Yuan, Chen Jianguo, Chen Laqiong, et al. Study of disperants for PP/nano CaCO3 blend[J]. China Plastics Industry, 2001,29(1):16~17,20(in Chinese) [27] 熊传溪,闻狄江,皮正杰.超微细Al2O3增韧增强聚苯乙烯的研究[J]. 高分子材料科学与工程,1994,7:69~73 Xiong Chuanxi, Wen Dijiang, Pi Zhengjie. Polystyrene toughened and strengened by ultrafine Al2O3 particles[J]. Polymeric Materials Science and Engineering, 1994,7:69~73(in Chinese)
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