Electrochemical characteristics of titanium alloy in engine oil and NaCl solution
-
摘要: 采用动电位扫描法研究了Ti-6Al-1.5Cr-2Zr钛合金在3#煤油和928滑油等高阻值油介质中的电化学极化特性.对于该新型钛合金电极在这2种航空油介质中自腐电位、极化电阻、腐蚀电流等电化学参数和相应的极化规律进行了研究.采用浸泡试验研究了该钛合金在3#煤油和928滑油中的腐蚀行为.结果表明钛合金在油介质中无明显腐蚀.对钛合金电极在高阻值油介质中电化学特性进行比较,研究了其在3.5%NaCl水溶液中的电化学行为,该钛合金电极在水溶液中的自腐蚀电位为-0.18V,在极化曲线上钝化区为0.27~1.24V,致钝电位为0.23V,致钝电流密度为0.31×10-4A/cm2.Abstract: The electrochemical characteristics of a new titanium alloy Ti-6Al-1.5Cr-2Zr in 3# kerosene and 928 lubricating oil with high resistance were studied by using potentiodynamic polarization. The electrochemical properties including the laws of polarization, open-circuit potential, linear polarization resistance and variation of corrosion current were investigated. The corrosion behaviors of titanium alloy were investigated by using immersion method in 3# kerosene and 928 lubricating oil. No visible corrosion appeared in the oil medium. The electrochemical characteristics of the alloy in 3.5% NaCl solution were also studied to compare that in the oil medium. The open-circuit potential was -0.18V, passivation potential was 0.23V, passivation current density was 0.31×10-4A/cm2 in 3.5%NaCl solution and the passivation area potential was in the range of 0.27~1.24V in 3.5% NaCl solution.
-
Key words:
- titanium alloys /
- electrochemistry /
- corrosion
-
[1] Garcia I, Fransaer J, Celis J P. Electrodeposition and sliding wear resistance of nickel composite coatings containing micron and submicron SiC particles[J]. Surface and Coatings Technology,2001,148:171~178 [2]Benea L, Bonora P L, Borello A, et al. Effect of SiC size dimensions on the corrosion wear resistance of the electrodeposited composite coating[J]. Materials and Corrosion,2002,53:23~29 [3]Nowak P, Socha R P, Kaisheva M, et al. Electrochemical investigation of the codeposition of SiC and SiO2 particles with nickel[J]. Journal of Applied Electrochemistry,2000,30(4):429~437 [4]Fransaer J, Celis J P. New insights into the mechanism of composite plating[J]. Galvanotechnik,2001,92(6):1544~1550 [5] 朱立群,李卫平,钟群鹏. ZrO2纳米微粉在Ni-W-B非晶态复合镀层中的作用研究[J]. 机械工程材料,1998,22(4):9~11 Zhu Liqun, Li Weiping, Zhong Qunpeng. Effect of ZrO2 particles in the electrodeposited Ni-W-B amorphous composite coatings[J]. Materials for Mechanical Engineering, 1998,22(4):9~11(in Chinese) [6] 李爱昌.(Ni-W)-ZrO2非晶复合镀层的制备及其性能[J]. 材料保护,2000,33(7):11~12,54 Li Aichang. Preparation of amorphous (Ni-W)-ZrO2 composite coating by electrodeposition[J].Materials Protection, 2000,33(7):11~12,54(in Chinese) [7] 禹 萍,苏玉长,谭澄宇,等. Ni-SiC和Ni-SiO2复合镀层性能的研究 . 表面技术,2001,30(3):27~29,44 Yu Ping, Su Yuchang, Tan Chengyu, et al. Study on properties of Ni-SiC and Ni-SiO2 composite plated coatings[J]. Surface Technology, 2001,30(3):27~29,44(in Chinese) [8] 徐龙堂,徐滨士,周美玲,等.电刷镀镍/镍包纳米Al2O3颗粒复合镀层微动磨损性能研究[J]. 摩擦学学报,2001, 21(1):24~27 Xu Longtang, Xu Binshi, Zhou Meiling, et al. Anti-fretting properties of Ni/Ni-coated nano-Al2O3 composite coating prepared by electro-brush plating[J]. Tribology, 2001, 21(1):24~27(in Chinese) [9] 吴元康.金刚石纳米晶在材料保护中的应用[J].材料保护,1995,28(4):15~17 Wu Yuankang. Application of diamond nanocrystal in material protection[J].Materials Protection, 1995,28(4):15~17(in Chinese) [10] 黄新民,吴玉程,郑玉春,等.纳米颗粒对复合镀层性能的影响[J].兵器材料科学与工程,1999,22(6):11~13 Huang Xinmin, Wu Yucheng, Zheng Yuchun,et al. Effect of nanometer particles on properties of electroless composite coatings[J]. Ordnance Material Science and Engineering, 1999, 22(6):11~13(in Chinese) [11] 谭澄宇,梁 英,夏长清,等.Ni-SiO2复合电镀层高温氧化性能研究 .表面技术,2000,29(6):16~19 Tan Chengyu, Liang Ying, Xia Changqing, et al. Research on the high temperature oxidation resistance of Ni/SiO2 composite deposit[J]. Surface Technology, 2000,29(6):16~19(in Chinese) [12] 朱立群,吴 俊,刘 峰,等.Cu-Zr合金基体上的复合镀层的性能研究 .材料工程,2001,(7):33~35 Zhu Liqun,Wu Jun,Liu Feng, et al. Study of the capability of the electrocomposite coating on the Cu-Zr alloy[J]. Journal of Materials Engineering, 2001,(7):33~35(in Chinese) [13] 黄 安,高 军,金勇杰,等.表面活性剂在复合电镀中作用研究[J].电镀与环保,1996,16(3):6~8 Huang An, Gao Jun, Jin Yongjie, et al. Effects of surfactants in composite plating[J]. Electroplating & Pollution Control, 1996,16(3):6~8(in Chinese) [14] 郭鹤桐,张三元.复合镀层[M].天津:天津大学出版社,1991 Guo Hetong, Zhang Sanyuan. Composite coating[M]. Tian Jin:Tian Jin University Press,1991(in Chinese)
点击查看大图
计量
- 文章访问数: 935
- HTML全文浏览量: 208
- PDF下载量: 3
- 被引次数: 0