Zr-Al-(Ni-Cu)合金的非晶形成能力及热学性能

张婧; 张涛

Zr-Al-(Ni-Cu)合金的非晶形成能力及热学性能

张婧,
张涛

北京航空航天大学材料科学与工程学院, 北京 100191

基金项目: 国家自然科学基金资助项目(50771006);国家自然科学基金重点资助项目(50631010)

详细信息

中图分类号: TG 139
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出版历程
- 收稿日期: 2009-04-26
- 网络出版日期: 2010-10-31

Glass forming ability and thermal stability of Zr-Al-(Ni-Cu) alloys

School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191, China

摘要

摘要: 采用喷射铜模铸造法研究了Ni和Cu含量对Zr-Al-(Ni-Cu)四元合金的非晶形成能力的影响.利用X射线衍射仪分析了铸态合金的相结构,利用差示扫描量热仪研究了非晶合金的热学性能.结果表明:Zr-Al-(Ni-Cu)四元合金的非晶形成能力远大于Zr-Al-Ni和Zr-Al-Cu三元合金的非晶形成能力.Zr₆₅Al_7.5Ni₁₀Cu_17.5合金显示最高的非晶形成能力,其非晶形成临界直径可以达到7mm.相似元素Ni和Cu在一定比例下共存,使液态合金的熵值增加,自由能降低,从而有效提高了合金的非晶形成能力.
- 非晶合金 /
- X射线衍射 /
- 非晶形成能力 /
- 热学性能 /
- 差示扫描量热法 /
- 相异相似元素共存原则
Abstract: Glass forming ability (GFA) of Zr-Al-(Ni-Cu) alloys with different Ni and Cu element contents was studied by injection copper mold casting method. Structures of the as-cast alloys, sliced along the cross-section, were identified by X-ray diffraction (XRD). Thermal properties of the bulk metallic glasses (BMG) were analyzed by differential scanning calorimetry (DSC). Results reveal that the critical diameters for glass formation of the ternary Zr-Al-Ni and Zr-Al-Cu alloys were highly improved by the coexistence of the similar elements (elements with similar atomic sizes and chemical properties) Ni and Cu in the quaternary Zr-Al-(Ni-Cu) alloys. For the Zr₆₅Al_7.5Ni₁₀Cu_17.5 alloy, which is the best glass former in the studied alloy system, BMG rod of 7mm in diameter was successfully synthesized. It is suggested that the significant improvement of GFA is attributed to the increase in the entropy and the decrease in free energy of the Ni and Cu substituted alloy systems.
- metallic glass /
- X ray diffraction /
- glass forming ability /
- thermal properties /
- differential scanning calorimetry /
- component coexistence criterion

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参考文献(1)

[1] Luborsky F E.Amorphous metallic alloys[M].London:Butterworth & Co (Publishers) Ltd,1983:1-7 [2] Egami T,Waseda Y.Atomic size effect on the formability of metallic glasses[J].J Non-Cryst Solids,1984,64(1/2):113-134 [3] Senkov O N,Miracle D B.Effect of the atomic size distribution on glass forming ability of amorphous metallic alloys[J].Mater Res Bulletin,2001,36(10):2183-2198 [4] Miracle D B,Senkov O N.Topological criterion for metallic glass formation[J].Mater Sci Eng A,2003,347(1):50-58 [5] Inoue A.Bulk amorphous alloys[M].Switzerland:Trans Tech Publications,1998:1-7 [6] Zhang T,Li R,Pang S J.Effect of similar elements on improving glass-forming ability of La Ce-based alloys[J].J Alloys Comp,2009,483(1/2):60-63 [7] Li R,Pang S J,Ma C L,et al.Influence of similar atom substitution on glass formation in (La-Ce)-Al-Co bulk metallic glasses[J].Acta Mater,2007,55:3719-3726 [8] Li R,Liu F J,Pang S J,et al.The influence of similar element coexistence in (La-Ce)-Al-(Co-Cu) bulk metallic glasses[J].Mater Trans,2007,48(7):1680-1683 [9] Zhuo L C,Pang S J,Wang H,et al.Ductile bulk aluminum-based alloy with good glass-forming ability and high strength[J].Chin Phys Lett,2009,26(6):066402 [10] Zhang Q S,Zhang W,Wang X M,et al.Structure,thermal stability and mechanical properties of Zr₆₅Al_7.5Ni₁₀Cu_17.5glassy alloy rod with a diameter of 16 mm produced by tilt casting[J].Mater Trans,2008,49(9):2141-2146 [11] Inoue A,Zhang T,Nishiyama N,et al.Preparation of 16 mm diameter rod of amorphous Zr₆₅Al_7.5Ni₁₀Cu_17.5 alloy[J].Mater Trans,1993,34:1234-1237 [12] Turnbull D.Under what conditions can a glass be formed[J].Contem Phys,1969,10(5):473-488 [13] Lu Z P,Liu C T.Glass formation criterion for various glass-forming systems[J].Phys Rev Lett,2003,91:115505-1-4 [14] Lu Z P,Liu C T.A new glass-forming ability criterion for bulk metallic glasses[J].Acta Mater,2002,50(13):3501-3512

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