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一种活性环氧增韧固化剂性能分析

杨洋 陈功

杨洋, 陈功. 一种活性环氧增韧固化剂性能分析[J]. 北京航空航天大学学报, 2007, 33(01): 119-122.
引用本文: 杨洋, 陈功. 一种活性环氧增韧固化剂性能分析[J]. 北京航空航天大学学报, 2007, 33(01): 119-122.
Yang Yang, Chen Gong. Analysis of the properties for epoxy curing agents with reactivity and toughening[J]. Journal of Beijing University of Aeronautics and Astronautics, 2007, 33(01): 119-122. (in Chinese)
Citation: Yang Yang, Chen Gong. Analysis of the properties for epoxy curing agents with reactivity and toughening[J]. Journal of Beijing University of Aeronautics and Astronautics, 2007, 33(01): 119-122. (in Chinese)

一种活性环氧增韧固化剂性能分析

详细信息
  • 中图分类号: TB 3

Analysis of the properties for epoxy curing agents with reactivity and toughening

  • 摘要: 以壬基酚和甲醛所形成的二聚体为原料,合成了一种新型结构的环氧固化剂双(2-羟基-3 -胺乙基胺甲基-5-壬基苯基)甲烷(BA),利用红外光谱(IR)、核磁共振谱(1HNMR)表征了产物结构.通过差 示扫描量热(DSC)研究了该固化剂的反应活性,确定固化剂最佳质量分数为43.19%.固化 树脂动态力学分析(DMA)表明,由于BA分子结构中存在正壬基,固化后会发生β- 松弛, 能够提高树脂韧性.力学性能测试发现BA固化树脂的冲击强度比普通芳香胺固化树脂提高了 36.91%,证明BA具有高活性和增韧双重效果.

     

  • [1] Frigione M E, Mascia L. Ollgomeric and polymeric modifiers for toughness of epo xy resins[J]. Eur Polym J, 1995, 31(11):1021-1029 [2] Moon. Epoxy curing agent of phenol aldehyde reacted with polyamine:US,WO 00/08082. 2000-02-17 [3] 程秀莲. T31固化剂制备新工艺[J].粘接, 2003, 24(6):28-30 Cheng XiuLian. New technology of preparation T31 curing agent[J]. Zhanjie,200 3,24(6):28-30(in Chinese) [4] Nifantev E E.Cyclophosphites from oilgomethylenephenols[J]. Rus sion Journal of General Chemistry,2002,72(6):903-908 [5] 杨洋.新型环氧固化剂的研究. 北京:北京航空航天大学材料科学与工程学院,2006 Yang Yang.Study on novel curing agents for epoxy resins. Beijing:School of Materials Science and Engineering,Beijing University of Aeronautics and Astrona utics,2006(in Chinese) [6] 叶朝阳.苯并噁嗪中间体/蛭石插层纳米复合物热固化行为的研究[J].高分子学报,2004,4(2):208-212 Ye Zhaoyang.Study on curing behavior of polybenzoxaine/vermiculite nanocomposit e[J].Acta Polmer Sinica,2004,4(2):208-212(in Chinese) [7] 徐卫兵.Avrami 法研究环氧树脂/蒙脱土/咪唑纳米复合材料的固化动力学[J].功能高分子学报,2001,14(3):66-70 Xu Weibing.Study on cure kinetics of epoxy resin/montmorillonite/imidazole nanoc omposite by avrami equation[J].Journal of Fuction Polymers,2001,14(3):66-70 (in Chinese) [8] 王德生.间苯二胺固化环氧树脂凝胶现象研究[J].西安交通大学学报,200 0,34(5):1-4 Wang Desheng. Gel phenomena of epoxy cured with metaphenylene diamine[J]. Jour nal of Xi′an Jiaotong University,2000,34(5):1-4(in Chinese) [9] Heux L,Halary J L.Dynamic mechanical and 13CNMR investigations of molecular motions involved in β relaxation of epoxy networks based on DGEBA an d aliphatic amines[J].Polymer,1997,38:1767-1778 [10] Bershtein V A,Peschanskaya N N.The sub-Tg relaxation in pure and antiplasticized model epoxy networks as studied by high resolution creep rate s pectroscopy[J].Polymer,1999,40:6687-6698
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出版历程
  • 收稿日期:  2006-01-19
  • 网络出版日期:  2007-01-31

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