激光光谱法尿素水溶液液膜多参数同步测量

石建伟; 吴威; 杨荟楠; 郭晓龙; 苏明旭; 蔡小舒

doi:10.13700/j.bh.1001-5965.2016.0101

激光光谱法尿素水溶液液膜多参数同步测量

doi: 10.13700/j.bh.1001-5965.2016.0101

石建伟^{1, 2},
吴威^{1, 2},
杨荟楠^{1, 2, ,},
郭晓龙^{1, 2},
苏明旭^{1, 2},
蔡小舒^{1, 2}

1.
上海理工大学能源与动力工程学院, 上海 200093
2.
上海市动力工程多相流动与传热重点实验室, 上海 200093

基金项目:

国家自然科学基金 51676130

国家自然科学基金 51306123

博士点基金联合资助课题 20133120120008

上海市科委科研计划 13DZ2260900

上海高校青年教师培养资助计划

详细信息

作者简介:
石建伟, 男, 硕士研究生。主要研究方向:激光光谱测量方法

通讯作者:
杨荟楠, 女, 博士, 副教授。主要研究方向:激光光谱测量方法与应用, E-mail:yanghuinan@usst.edu.cn

中图分类号: TK311
计量
- 文章访问数: 726
- HTML全文浏览量: 97
- PDF下载量: 454
- 被引次数: 0
出版历程
- 收稿日期: 2016-01-26
- 录用日期: 2016-06-02
- 网络出版日期: 2017-02-20

Simultaneous measurement of multi-parameter of liquid film for urea-water-solution by laser spectroscopy

SHI Jianwei^{1, 2},
WU Wei^{1, 2},
YANG Huinan^{1, 2
, ,},
GUO Xiaolong^{1, 2},
SU Mingxu^{1, 2},
CAI Xiaoshu^{1, 2}

1.
School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
2.
Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering, Shanghai 200093, China

Funds:

National Nature Science Foundation of China 51676130

National Nature Science Foundation of China 51306123

the Joint Specialized Research Found for the Doctoral Program of Higher Education 20133120120008

Research Project of Shanghai Municipal Science and Technology 13DZ2260900

Cultivation of Young Teachers in Colleges and Universities Funded Program in Shanghai

More Information

Corresponding author: YANG, HuinanE-mail:yanghuinan@usst.edu.cn

摘要

摘要:
对溶液液膜温度、厚度和浓度进行定量分析对与之相关的工业过程至关重要，对其机理的研究中它们互相耦合，而传统的测量方法只能实现液膜的温度、厚度和浓度的单独测量。本文基于比尔-朗伯定律，提出一种尿素水溶液液膜的温度、厚度和浓度同步测量新方法，通过结合3个波长1 420、1 488和1 531 nm的激光，建立了尿素水溶液液膜的温度、厚度和浓度的同步反演模型。在此基础上，利用1 mm温控样品池验证了该方法的测量精度，结果表明，该方法测量尿素水溶液液膜厚度的平均误差为0.51%，液膜温度的平均误差为2.59%，液膜浓度的平均误差为6.32%。
- 激光光谱 /
- 液膜 /
- 厚度 /
- 温度 /
- 浓度
Abstract:
Quantitative analysis of liquid film temperature, thickness and mass fraction is extremely crucial to the relevant industrial processes, and these parameters are mutually coupled in the study of the mechanism for heat transfer. Temperature, thickness and mass fraction of liquid film, however, can only be determined individually by conventional measurement techniques. In this paper, a novel measurement method based on Beer-Lambert law to measure the film temperature, thickness and mass fraction of urea-water-solution simultaneously was developed by combining three lasers with different wavelengths:1 420, 1 488 and 1 531 nm. In addition, measurement accuracy of this method was validated by a sample cell with controlled temperature and 1 mm optical path length. The experimental results reveal that average relative errors of thickness, temperature and mass fraction of urea-water-solutions measured by the developed method are 0.51%, 2.59% and 6.32%, respectively.
- laser spectroscopy /
- liquid film /
- thickness /
- temperature /
- mass fraction

HTML全文

图 1 温度30℃，不同浓度(5%~35%) 以及浓度10%不同温度(25~50℃) 的尿素水溶液吸收光谱

Figure 1. Absorption spectra of urea-water-solution with different mass fraction (5% -35%) at 30℃ and with mass fraction of 10% at different temperature (25-50℃)

下载: 全尺寸图片幻灯片

图 2 实验装置图

Figure 2. Schematic drawing of experimental setup

下载: 全尺寸图片幻灯片

图 3 尿素水溶液液膜厚度、浓度及温度反演结果

Figure 3. Calculated results of film thickness, mass fraction and temperature for urea-water-solution

下载: 全尺寸图片幻灯片

表 1 3个波长所对应的A_i、B_i、D_i、E_i的值

Table 1. Values of A_i、B_i、D_i、E_i at three corresponding wavelengths

波长/nm	A_i	B_i	D_i	E_i
1 420	-0.052 33	-8.446 49	0.048 91	10.430 74
1 488	0.067 71	-0.713 14	-0.048 41	11.484 23
1 531	0.029 85	-2.452 57	-0.036 21	6.917 73

下载: 导出CSV

参考文献(18)

[1]	SUN Y Z, SONG X F, JIN M M, et al.Gas-liquid reactive crystallization of lithium carbonate by a falling film column[J].Industrial Engineering Chemistry Research, 2013, 52(49):17598-17606. doi: 10.1021/ie402698v
[2]	PAUTSCH A G, SHEDD T A, NELLIS G F.Thickness measurements of the thin film in spray evaporative cooling[C]//9th Intersociety Conference on Thermal and Thermomechanical Phenomena in Electronic Systems.Piscataway, NJ:IEEE Press, 2004, 1:70-76.
[3]	MAWHINNEY J R, RICHARDSON J K.A review of water mist fire suppression research and development[J].Fire Technology, 1996, 33(1):54-90. https://www.researchgate.net/publication/226216383_A_Review_of_Water_Mist_Fire_Suppression_Research_and_Development_1996
[4]	KAY K Y, ASTERIOS G, RALF Z, et al.Catalyst preparation and deactivation issues for nitrobenzene hydrogenation in a microstructure falling film reactor[J].Catalysis Today, 2003, 81(4):641-651. doi: 10.1016/S0920-5861(03)00162-7
[5]	苏风民, 马鸿斌, 高洪涛, 等.基于薄液膜蒸发的超高速冷冻方法初探[J].工程热物理学报, 2014, 35(3):538-540. http://www.cnki.com.cn/Article/CJFDTOTAL-GCRB201403028.htm SU F M, MA H B, GAO H T, et al.Preliminary study of ultra-fast cooling methods utilizing thin film evaporation[J].Journal of Engineering Thermophysics, 2014, 35(3):538-540(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-GCRB201403028.htm
[6]	陈世昌, 马建平, 张先明, 等.竖直降液膜流动在反应工程中的应用[J].化工进展, 2014, 33(10):2528-2534. http://www.cnki.com.cn/Article/CJFDTOTAL-HGJZ201410002.htm CHEN S C, MA J P, ZHANG X M, et al.Advances in application of falling liquid film for reaction engineering[J].Chemical Industry and Engineering Progress, 2014, 33(10):2528-2534(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-HGJZ201410002.htm
[7]	戴干策.化学工程基础:流体流动、传热及传质[M].北京:中国石化出版社, 1991:25-32. DAI G C.Chemical engineering foundation:Fluid flow, heat transfer and mass transfer[M].Beijing:China Petrochemical Press, 1991:25-32(in Chinese).
[8]	BIRKHOLD F, MEINGAST U, WASSERMANN P, et al.Analysis of the injection of urea-water-solution for automotive SCR DeNO_x-systems:Modeling of two-phase flow and spray/wall-interaction:2006-01-0643[R].Warrendale, PA:SAE International, 2006.
[9]	陈冯, 王谦, 何志霞, 等.柴油机尿素Urea-SCR喷射过程参数优化及数值模拟研究[J].内燃机工程, 2015, 36(1): 23-30. http://www.cnki.com.cn/Article/CJFDTOTAL-NRJG201501005.htm CHEN F, WANG Q, HE Z X, et al.Optimization and numerical simulation of urea spray parameters in diesel engine SCR system[J].Chinese Internal Combustion Engine Engineering, 2015, 36(1):23-30(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-NRJG201501005.htm
[10]	余皎, 王军, 佟德辉, 等.重型柴油机SCR系统布置优化设计[J].内燃机与动力装置, 2010(4):25-29. http://www.cnki.com.cn/Article/CJFDTOTAL-SDNR201004008.htm YU J, WANG J, TONG D H, et al.Configuration optimization of the SCR system for a heavy duty dieset engine[J].Internal Combustion Engine and Power Plant, 2010(4):25-29(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-SDNR201004008.htm
[11]	喻小伟, 李宇春, 蒋娅, 等.尿素热解研究及其在脱硝中的应用[J].热力发电, 2012, 41(1):1-5. http://www.cnki.com.cn/Article/CJFDTOTAL-RLFD201201002.htm YU X W, LI Y C, JIANG Y, et al.Study on pyrolysis of urea and its application in denitrifcation[J].Thermal Power Generation, 2012, 41(1):1-5(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-RLFD201201002.htm
[12]	崔洁, 陈雪莉, 王清立, 等.电导法测量新型旋风分离器内液膜的分布规律[J].化工学报, 2009, 60(6):1487-1493. http://www.cnki.com.cn/Article/CJFDTOTAL-HGSZ200906025.htm CUI J, CHEN X L, WANG Q L, et al.Double-parallel conductance probe for measuring thickness of liquid film in new-type cyclone separator[J].Journal of Chemical Industry and Engineering, 2009, 60(6):1487-1493(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-HGSZ200906025.htm
[13]	张锋, 耿皎, 马少玲, 等.利用电容法测量降膜厚度[J].测量与设备, 2005(4):34-35. http://www.cnki.com.cn/Article/CJFDTOTAL-JLJS200505013.htm ZHANG F, GENG J, MA S L, et al.Measurement of the falling film thickness by capacitance method[J].Measurement and Equipment, 2005(4):34-35(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-JLJS200505013.htm
[14]	郑丽行, 樊小林, 刘刚, 等.折光率测定尿素含量的方法研究[J].西北农林科技大学学报(自然科学版), 2010, 38(12):93-98. http://www.cnki.com.cn/Article/CJFDTOTAL-XBNY201012017.htm ZHENG L X, FAN X L, LIU G, et al.Study on refractive index method for determination of urea concentration[J]. Journal of Northwest A & F University (Natural Science Edition), 2010, 38(12):93-98(in Chinese). http://www.cnki.com.cn/Article/CJFDTOTAL-XBNY201012017.htm
[15]	YANG H, GRESZIK D, DREIER T, et al.Simultaneous measurement of liquid water film thickness and vapor temperature using near-infrared tunable diode laser spectroscopy[J].Applied Physics B:Lasers and Optics, 2010, 99(3):385-390. doi: 10.1007/s00340-010-3980-3
[16]	HALBOUT J M, BLIT S, DONADSON W, et al.Efficient phase-matched second-harmonic generation and sum-frequency mixing in urea[J].IEEE Journal of Quantum Electronics, 1979, 15(10):1176-1180. doi: 10.1109/JQE.1979.1069900
[17]	YANG H N, GUO X L, SU M X, et al.Novel method for simultaneous measurement of film thickness and mass fraction of urea-water solution[J].Chinese Optics Letters, 2014, 12(12):123102. doi: 10.3788/COL
[18]	YANG H N, GUO X L, ZHOU W, et al. Investigation on liquid film of urea-water solutions with diode laser absorption spectroscopy[J].Experiments in Fluids, 2015, 56(4):73-1-73-7. doi: 10.1007/s00348-015-1941-7