The high temperature gas after shock wave occurs to ionize in hypersonic flight, which makes the aerodynamic thermal environments to be complicated. The 5 species (N2, O2, NO, O, N), 7 species (N2, O2, NO, O, N, NO+, e-) and 11 species (N2, O2, NO, O, N, N2+, O2+, NO+, O+, N+, e-) thermo-chemical re...